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Фам К. Н., Горбунов Р. В., Лапченко В. А., Горбунова Т. Ю., Табунщик В. А. Химический состав снежного покрова в лесных экосистемах Крыма: на примере Карадагского природного заповедника // Биоразнообразие и устойчивое развитие. 2026. Т. 11, № 2. С. 58-78. https://doi.org/10.21072/eco.2026.11.2.06

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Аннотация

Целью исследования является анализ химического состава снежного покрова и распределения макроэлементов в нём на территории Карадагского природного заповедника (Крым), где снегопады редки. Пробы снега, отобранные в зимний период с 2021 по 2024 год на фоновой станции экологического мониторинга, проанализированы на содержание ионов и кислотность. Выявлено, что кислотность варьирует от 6,00 до 7,46 с преобладанием сульфатов, что свидетельствует об антропогенном влиянии. Химический состав определяется как природными, так и антропогенными факторами. Высокое соотношение катионов к анионам указывает на буферные процессы, снижающие кислотность, что может положительно влиять на экосистему. Результаты подчёркивают необходимость мониторинга атмосферных осадков для оценки антропогенных воздействий.

Авторы

К. Н. Фам

кандидат химических наук, старший научный сотрудник

Р. В. Горбунов

доктор географических наук, директор, главный научный сотрудник 

В. А. Лапченко

научный сотрудник 

Т. Ю. Горбунова

кандидат географических наук, старший научный сотрудник 

В. А. Табунщик

кандидат географических наук, старший научный сотрудник 

Библиографические ссылки

Al-Momani I. F. Trace elements in atmospheric precipitation at Northern Jordan measured by ICP-MS: acidity and possible sources // Atmospheric Environment. – 2003. – Vol. 37, iss. 32. – P. 4507–4515. – https://doi.org/10.1016/S1352-2310(03)00562-4

Aničić M., Tasić M., Frontasyeva M. V., Tomašević M., Rajšić S., Mijić Z., Popović A. Active moss biomonitoring of trace elements with Sphagnum girgensohnii moss bags in relation to atmospheric bulk deposition in Belgrade, Serbia // Environmental Pollution. – 2009. – Vol. 157, iss. 2. – P. 673–679. – https://doi.org/10.1016/j.envpol.2008.08.003

Aristarain A. J., Delmas R. J. Snow chemistry measurements on James Ross Island (Antarctic Peninsula) showing sea salt aerosol modifications // Atmospheric Environment. – 2002. – Vol. 36, iss. 4. – P. 765–772. – https://doi.org/10.1016/S1352-2310(01)00362-4

Benassai S., Becagli S., Gragnani R., Magand O., Proposito M., Fattori I., Traversi R., Udisti R. Sea-spray deposition in Antarctic coastal and plateau areas from ITASE traverses // Annals of Glaciology. – 2005. – Vol. 41. – P. 32–40. – https://doi.org/10.3189/172756405781813285

Cao J., Tie X., Dabberdt W. F., Jie T., Zhao Z., An Z., Shen Z., Feng Y. On the potential high acid deposition in northeastern China // Journal of Geophysical Research: Atmospheres. – 2013. – Vol. 118, iss. 10. – P. 4834–4846. – https://doi.org/10.1002/jgrd.50381

Chudaeva V. A., Chudaev O. V., Yurchenko S. G. Chemical composition of precipitation in the southern part of the Russian Far East // Water Resources. – 2008. – Vol. 35. – P. 58–70. – https://doi.org/10.1134/s0097807808010077

de Caritat P., Hall G., Gíslason S., Belsey W., Braun M., Goloubeva N. I., Olsen H. K., Scheie J. O., Vaive J. E. Chemical composition of Arctic snow: concentration levels and regional distribution of major elements // Science of The Total Environment. – 2005. – Vol. 336, iss. 1/3. – P. 183–199. – https://doi.org/10.1016/j.scitotenv.2004.05.031

Dibb J. E., Ziemba L. D., Luxford J., Beckman P. Bromide and other ions in the snow, firn air, and atmospheric boundary layer at Summit during GSHOX // Atmospheric Chemistry and Physics. – 2010. – Vol. 10, iss. 20. – P. 9931–9942. – https://doi.org/10.5194/acp-10-9931-2010

Domine F., Sparapani R., Ianniello A., Beine H. J. The origin of sea salt in snow on Arctic sea ice and in coastal regions // Atmospheric Chemistry and Physics. – 2004. – Vol. 4, iss. 9/10. – P. 2259–2271. – https://doi.org/10.5194/acp-4-2259-2004

Duan L., Yu Q., Zhang Q., Wang Z., Pan Y., Larssen T., Tang J., Mulder J. Acid deposition in Asia: Emissions, deposition, and ecosystem effects // Atmospheric Environment. – 2016. – Vol. 146. – P. 55–69. – https://doi.org/10.1016/j.atmosenv.2016.07.018

Eremina I. D., Grigoriev A. V. Acidity and chemical composition of snow cover in the city of Moscow and the Moscow Region during 1999–2006 // Lomonosov Geography Journal. – 2010. – № 3. – P. 55–60. – https://elibrary.ru/mvxlph. (in Russian)

Gladun I. V., Shelganova A. A., Mayorova L. P. Technogenic pollution of snow cover in the Khabarovsk Territory in the period from 2015 to 2022 // The Eurasian Scientific Journal. – 2024. – Vol. 16, nr 3. – Art. 94NZVN324. (in Russian)

Glazovsky N. F., Zlobina A. I., Uchvatov V. P. Chemical composition of the snow cover in some parts of the upper Oka basin // Regional Ecological Monitoring / eds: V. E. Sokolov [et al.]. – Moscow : Nauka, 1983. – P. 67–86. (in Russian)

GN 2.1.5.1315-03. Ob utverzhdenii sanitarnykh pravil i norm SanPiN 1.2.3685-21 “Gigienicheskie normativy i trebovaniya k obespecheniyu bezopasnosti i (ili) bezvrednosti dlya cheloveka faktorov sredy obitaniya” : postanovlenie Gl. gos. sanit. vracha RF № 2 ot 28.01.2021 // Ofitsialʹnyj internet-portal pravovoj informatsii. – 2021. – URL: http://publica-tion.pravo.gov.ru/document/0001202102030022?index=1 (data obrashcheniya: 12.02.25).

Grannas A. M., Jones A. E., Dibb J. [et al.]. An overview of snow photochemistry: evidence, mechanisms and impacts // Atmospheric Chemistry and Physics. – 2007. – Vol. 7, iss. 16. – P. 4329–4373. – https://doi.org/10.5194/acp-7-4329-2007

Gurov K. I, Kotelyanets E. A. Distribution of trace metals (Cr, Cu, Ni, Pb, Zn, Sr, Ti, Mn and Fe) in the vertical section of bottom sediments in the Sevastopol Bay (Black Sea) // Physical Oceanography. – 2022 – Vol. 29, iss. 5. – P. 491–507 – https://doi.org/10.22449/1573-160X-2022-5-491-507

Honrath R. E., Peterson M. C., Dziobak M. P., Dibb J. E., Arsenault M. A., Green S. A. Release of NOx from sunlight-irradiated mid-latitude snow // Geophysical Research Letter. – 2000. – Vol. 27, iss. 15. – P. 2237–2240. – https://doi.org/10.1029/1999GL011286

Honrath R. E., Peterson M. C., Guo S., Dibb J. E., Shepson P. B., Campbell B. Evidence of NOx production within or upon ice particles in the Greenland snowpack // Geophysical Research Letter. – 1999. – Vol. 26, iss. 6. – P. 695–698. – https://doi.org/10.1029/1999GL900077

Hunova I., Kurfürst P., Schreiberová M., Vlasáková L., Škáchová H. Atmospheric deposition of lead and cadmium in a Central European country over the last three decades // Atmosphere. – 2023. – Vol. 14, iss. 1. – Art. 19. – https://doi.org/10.3390/atmos14010019

Karpachevskiy L. O., Zubkova T. A., Proysler T., Kennel M., Gittel G., Gorcharuk N. Yu., Minaeva T. Yu. Impact of a complex spruce forest canopy on the chemical composition of precipitation // Lesovedenie. – 1998. – № 1. – S. 50–59.

Katanayeva V. G., Selyanin A. V. Estimation of heavy metals content and their inflow into the salt lakes of forest-steppe in the right-bank Priishimye // Vestnik Tyumenskogo Gosudarstvennogo Universiteta. Ekologiya i Prirodopol’zovanie. – 2011. – № 5. – S. 39–48. – https://elibrary.ru/ofyood (in Russian)

Kaya G., Tuncel G. Trace element and major ion composition of wet and dry deposition in Ankara, Turkey // Atmospheric Environment. – 1997. – Vol. 31, iss. 23. – P. 3985–3998. – https://doi.org/10.1016/S1352-2310(97)00221-5

Kayukova E. P. Features of the chemical composition of precipitation of the Crimean training site of SPbSU // Vestnik Sankt-Peterburgskogo Universiteta. Ser. 7, Geologiya. Geografiya – 2011. – № 3. – С. 26–42. (in Russian)

Kotova E. I., Topchaya V. Yu., Novikova Yu. V. Geobiochemical characteristics of snow cover on the White Sea coast in 2021 and 2022 // Water Resources. – 2023. – Vol. 50, iss. 1. – P. 80–88. – https://doi.org/10.1134/S0097807823700306

Krnavek L., Simpson W. R., Carlson D., Domine F., Douglas T. A., Sturm M. The chemical composition of surface snow in the Arctic: Examining marine, terrestrial, and atmospheric influences // Atmospheric Environment. – 2012. – Vol. 50. – P. 349–359. – https://doi.org/10.1016/j.atmosenv.2011.11.033

Kulikova V. K. Leaching of nutrient elements from tree crowns in spruce and birch-spruce plantations of Karelia // Les i pochva : Trudy vsesoyuz. nauch. konf. po les. pochvove-deniyu, 15–19 iyulya 1965 g. / otv. red. N. V. Orlovskij. – Krasnoyarsk : Kn. izd-vo, 1968. – S. 288–295.

Kurosaki Y., Matoba S., Matsumoto M., Yamasaki T., Hendriksen I., Iizuka Yo. Characteristics of snowpack chemistry on the coastal region in the northwestern Greenland Ice Sheet facing the North Water, EGUsphere : [preprint]. – 2025. – https://doi.org/10.5194/egusphere-2025-1560

Lipatnikova O. A., Lubkova T. N., Yablonskaya D. A., Dmitriev L. A. Geokhimicheskaya kharakteristika vod rodnikov yuzhnoi chasti gorodskogo okruga Balashikha (Moskovskaya oblast’) // Vodnye Resursy. – 2024. – T. 51, № 1. – S. 101–114. – https://doi.org/10.31857/S0321059624010095

Makarov V. N., Torgovkin N. V. Ecological and geochemical characteristics of the snow cover in the Yakutsk city (Central Siberia) // Ice and Snow. – 2021. – Vol. 61, iss. 3. – P. 420–430. – https://doi.org/10.31857/S2076673421030098

Moody J. L., Samson P. J. The influence of atmospheric transport on precipitation chemistry at two sites in the midwestern United States // Atmospheric Environment (1967). – 1989. – Vol. 23, iss. 10. – P. 2117–2132. – https://doi.org/10.1016/0004-6981(89)90173-X

Nickus U. Ion content of the snowpack on Franz Josef Land, Russia // Arctic, Antarctic, and Alpine Research. – 2003. – Vol. 35, iss. 3. – P. 399–408. – https://www.elibrary.ru/lzkssh

Pham C. N., Gorbunov R., Lapchenko V., Gorbunova T., Tabunshchik V. Macro- and microelements and the impact of submediterranean downy oak forest communities on their composition in rainwater // Forests. – 2024. – Vol. 15, iss. 4. – Art. 612. – https://doi.org/10.3390/f15040612

Poissant L., Schmit J.-P., Béron P. Trace inorganic elements in rainfall in the Montreal Island // Atmospheric Environment. – 1994. – Vol. 28, iss. 2. – P. 339–346. – https://doi.org/10.1016/1352-2310(94)90109-0

Pristova T. A., Vasilevich M. I. Chemical composition of snow cover in middle-taiga forest ecosystems in the Komi Republic // Geochemistry International. – 2011. – Vol. 49, iss. 2. – P. 199–206. – https://doi.org/10.1134/s001670291012102x

Radomskaya V. I., Yusupov D. V., Pavlova L. M. Macrocomponent composition of snow cover of Blagoveshchensk city // Voda: khimiya i ekologiya. – 2014. – № 8. – S. 95–103. – https://www.elibrary.ru/stwqut (in Russian)

RD 52.04.186-89. Rukovodstvo po kontrolyu zagryazneniya atmosfery : data vved. 1991-07-01 / razrab. Gos. kom. SSSR po gidrometeorologii i M-vom zdravookhraneniya SSSR // Kodeks : el. fond pravovykh i normat.-tekhn. dokumentov. – URL: https://docs.cntd.ru/document/1200036406? ysclid=mqpe3uv741387816858 (data obrashcheniya: 12.02.25).

Sanina N. B., Sklyarova O. A., Kostin S. B. Geochemical study of snow cover in the Baikal Biosphere Preserve (in connection with degrading fir trees on the northern slope of the Khamar-Daban Mountain Ridge) // Geoekologiya. Inzhenernaya geologiya, gidrogeologiya, geokriologiya. – 2003. – № 2. – S. 120–129. – https://www.elibrary.ru/ndnuun (in Russian)

Stachurski A., Zimka J. R. Atmospheric input of elements to forest ecosystems: a method of estimation using artificial foliage placed above rain collectors // Environmental Pollution. – 2000. – Vol. 110, iss. 2. – P. 345–356. – https://doi.org/10.1016/S0269-7491(99)00290-0

Surkova G. V., Eremina I. D., Zorina S. A. Vliyanie kontinentalʹnykh i morskikh istochnikov na khimicheskij sostav letnikh atmosfernykh osadkov severo-vostochnogo poberezhʹya Chernogo morya // Ekologicheskaya bezopasnostʹ pribrezhnoj i shelʹfovoj zon i kompleksnoe ispolʹzovanie resursov shelʹfa / Mor. gidrofiz. in-t RAN. – Sevastopolʹ : MGI, 2005. – № 12. – S. 208–214. – https://www.elibrary.ru/tgyvwf

Toom-Sauntry D., Barrie L. A. Chemical composition of snowfall in the high Arctic: 1990–1994 // Atmospheric Environment. – 2002. – Vol. 36, iss. 15/16. – P. 2683–2693. – https://doi.org/10.1016/S1352-2310(02)00115-2

Topchaya V. Yu., Kotova E. I., Starodymova D. P., Chechko V. A. Distribution, material and chemical composition of sedimentary matter of rainfall on the territory of the Kaliningrad Region RF // Advances in Current Natural Sciences – 2020. – № 1. – S. 47–53. – https://doi.org/10.17513/use.37320 (in Russian).

Trushkina L. Yu., Trushkin A. G., Demyanova L. M. Gigiena i ekologiya cheloveka. – 4-e izd. – Moskva : Prospekt, 2006 – 527 p.

Vasilevich M. I., Beznosikod [i. e. Beznosikov] V. A., Kondratenok B. M. Chemical composition of snow cover in the taiga zone of the Komi Republic // Water Resources. – 2011. – Vol. 38, iss. 4. – P. 530–542. – https://doi.org/10.1134/S0097807811040130

Vet R., Artz R. S., Carou S. [et al.]. A global assessment of precipitation chemistry and deposition of sulfur, nitrogen, sea salt, base cations, organic acids, acidity and pH, and phosphorus // Atmospheric Environment. – 2014. – Vol. 93. – P. 3–100. – https://doi.org/10.1016/j.atmosenv.2013.10.060

Vinogradov A. P. Vvedenie v geokhimiyu okeana. – Moskva : Nauka, 1967. – 215 p.

Weeks W. F., Ackley S. F. The growth, structure, and properties of sea ice // The Geophysics of sea ice / ed. N. Untersteiner. – New York : Plenum Press, 1986. – P. 9–161. – (NATO ASI Series. Ser. B, Physics ; vol. 146). – https://doi.org/10.1007/978-1-4899-5352-0_2

Xue H., Chen W., Li M., Liu B., Li G., Han X. Assessment of major ions and trace elements in snow: A case study across northeastern China, 2017–2018 // Chemosphere. – 2020. – Vol. 251. – Art. 126328 – https://doi.org/10.1016/j.chemosphere.2020.126328

Yalcin K., Wake C. P., Dibb J. E., Whitlow S. I. Relationships between aerosol and snow chemistry at King Col, Mt. Logan Massif, Yukon, Canada // Atmospheric Environment. – 2006. – Vol. 40, iss. 37. – P. 7152–7163. – https://doi.org/10.1016/j.atmosenv.2006.06.028

Yudovich Ya. E., Ketris M. P. Toxic trace elements in coal. – Ekaterinburg : Institute of Geology Komi SC UB RAS, 2005. – 655 p. (in Russian)

Zverev V. P., Varvanina O. Yu., Putilina V. S. Zakonomernosti izmeneniya sostava atmosfernykh osadkov na territorii Rossii // Geoekologiya. Inzhenernaya geologiya, gidrogeologiya, geokriologiya. – 1997. – № 5. – S. 30–38.

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This work was carried out within the framework of the IBSS state research assignment, registration number: 124030100030-0, and of KSS – NR RAS – Branch of IBSS, registration number: 124030100098-0.

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